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Organophotocatalysis in nanostructured soft gel materials as tunable reaction vessels: comparison with homogeneous and micellar solutions

Bachl, Jürgen ; Hohenleutner, Andreas ; Dhar, Basab Bijayi ; Cativiela, Carlos ; Maitra, Uday ; König, Burkhard ; Diaz Diaz, David



Abstract

Riboflavin tetraacetate-catalyzed aerobic photooxidation of 1-(4-methoxyphenyl)ethanol was investigated as a model reaction under blue visible light in different soft gel materials, aiming to establish their potential as reaction vessels for photochemical transformations. Three strategies involving different degrees of organization of the catalyst within the gel network were explored, and the ...

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