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Hydration and ion pairing of aqueous phosphate solutions as observed by dielectric spectroscopy

Eiberweiser, Andreas (2013) Hydration and ion pairing of aqueous phosphate solutions as observed by dielectric spectroscopy. PhD, Universität Regensburg.

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Date of publication of this fulltext: 17 Jun 2013 09:45

Abstract (English)

The present thesis represents the first detailed DRS study (25°C, 0.2 ≤ ν/GHz ≤ 89) of inorganic phosphate hydration and ion-pairing. To gain more insight into the physical origin of a low-amplitude low-frequency mode frequently present in electrolyte solutions also aqueous NaCl solutions were investigated. The complete series of potassium phosphates was investigated in order to extract detailed ...

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Translation of the abstract (German)

Die vorliegende Dissertation stellt die erste detaillierte DRS-Studie (25°C, 0.2 ≤ ν/GHz ≤ 89) über die Hydratation und Ionenpaarbildung anorganischer Phosphatsalzlösungen dar. Um mehr Informationen über den Ursprung einer niederfrequenten Mode mit niedriger Amplitude, welche häufig in Elektrolytlösungen auftritt, zu erhalten, wurden ebenfalls wässrige NaCl-Lösungen untersucht. Das Studium der ...

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Item type:Thesis of the University of Regensburg (PhD)
Date:17 June 2013
Referee:apl. Prof. Dr Richard Buchner
Date of exam:12 April 2013
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Keywords:dielectric relaxation spectroscopy, phosphates, ion specific hofmeister effects, sodium chloride, ion pairing, ion-pair relaxation, ion-cloud relaxation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:28377
Owner only: item control page

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