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Hydration and ion pairing of aqueous phosphate solutions as observed by dielectric spectroscopy

URN to cite this document:
urn:nbn:de:bvb:355-epub-283773
Eiberweiser, Andreas
Date of publication of this fulltext: 17 Jun 2013 09:45


Abstract (English)

The present thesis represents the first detailed DRS study (25°C, 0.2 ≤ ν/GHz ≤ 89) of inorganic phosphate hydration and ion-pairing. To gain more insight into the physical origin of a low-amplitude low-frequency mode frequently present in electrolyte solutions also aqueous NaCl solutions were investigated. The complete series of potassium phosphates was investigated in order to extract detailed ...

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Translation of the abstract (German)

Die vorliegende Dissertation stellt die erste detaillierte DRS-Studie (25°C, 0.2 ≤ ν/GHz ≤ 89) über die Hydratation und Ionenpaarbildung anorganischer Phosphatsalzlösungen dar. Um mehr Informationen über den Ursprung einer niederfrequenten Mode mit niedriger Amplitude, welche häufig in Elektrolytlösungen auftritt, zu erhalten, wurden ebenfalls wässrige NaCl-Lösungen untersucht. Das Studium der ...

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