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Photokatalyse mit [Cu(dap)2Cl] und sichtbarem Licht

URN to cite this document:
urn:nbn:de:bvb:355-epub-284458
Pirtsch, Michael
Date of publication of this fulltext: 30 Jun 2014 13:07


Abstract (German)

Im Rahmen der vorliegenden Arbeit wurde mit [Cu(dap)2Cl] (dap = 2,9-Bis-(4-methoxy-phenyl)-1,10-phenanthrolin) eine Alternative zu etablierten Photoredoxkatalysatoren und Photosensitizern wie [Ru(BiPy)3]Cl2 (BiPy = 2,2‘-Bipyridin) und zu verwandten, auf Iridium basierenden Komplexen untersucht. Der erstmals 1987 von Sauvage et al. beschriebene Komplex [Cu(dap)2Cl] weist im UV-Spektrum starke ...

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Translation of the abstract (English)

Within this work, [Cu(dap)2Cl] (dap = 2,9-Bis-(4-methoxy-phenyl)-1,10-phenanthroline) was tested as an operational alternative to well established photoredox catalysts and photosensitizers, such as [Ru(BiPy)3]Cl2 (BiPy = 2,2‘-Bipyridine) or related, iridium based complexes. First described by Sauvage et al. in 1987, [Cu(dap)2Cl] exhibits broad absorption in the UV-spectrum between 400 and 600 nm, ...

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