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First Determination of the Rate Acceleration of a Palladium Catalyzed Coupling Reaction by High Pressure

Hillers, Stephan ; Reiser, Oliver



Abstract

The activation volume, ΔV‡, reflecting the rate acceleration by pressure, of the coupling reaction between 2,3-dihydrofuran and iodobenzene is determined as –12 ± 2 cm⁻³ by kinetic measurements at pressures between 1 bar and 8 kbar; moreover, our kinetic data suggest that the rate-determining step is not the oxidative addition of iodobenzene to the palladium catalyst.


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