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Synthesis and Phase Relations of Single-Phase Fibrous Phosphorus

Eckstein, Nadine ; Hohmann, Andrea ; Weihrich, Richard ; Nilges, Tom ; Schmidt, Peer


Fibrous phosphorus is one of the known crystalline allotropes under standard pressure conditions. It has been predicted prior to its successful synthesis and structural characterization. The allotrope consists of parallel, tubular double strands of phosphorus, in contrast to the violet form of Hittorf's phosphorus, where the same strands are arranged in a perpendicular orientation towards each ...


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