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Schnelle, W. ; Leithe-Jasper, A. ; Rosner, H. ; Schappacher, F.M. ; Pöttgen, R. ; Pielnhofer, F. ; Weihrich, Richard

Ferromagnetic ordering and half-metallic state of Sn2Co3S2 with the shandite-type structure

Schnelle, W., Leithe-Jasper, A., Rosner, H., Schappacher, F.M., Pöttgen, R., Pielnhofer, F. and Weihrich, Richard (2013) Ferromagnetic ordering and half-metallic state of Sn2Co3S2 with the shandite-type structure. Physical Review B (PRB) 88, p. 144404.

Date of publication of this fulltext: 18 Oct 2013 07:47
Article
DOI to cite this document: 10.5283/epub.28932


Abstract

Single crystalline Sn2Co3S2 with the shandite-type structure was investigated by magnetization, magnetoresistance, Hall effect, and heat capacity measurements and by Sn-119 Mossbauer spectroscopy. Sn2Co3S2 orders ferromagnetically at 172 K with an easy-axis magnetization of approximate to 1 mu(B) along the hexagonal c axis. The half-metallic ferromagnetic state is investigated by detailed ...

Single crystalline Sn2Co3S2 with the shandite-type structure was investigated by magnetization, magnetoresistance, Hall effect, and heat capacity measurements and by Sn-119 Mossbauer spectroscopy. Sn2Co3S2 orders ferromagnetically at 172 K with an easy-axis magnetization of approximate to 1 mu(B) along the hexagonal c axis. The half-metallic ferromagnetic state is investigated by detailed band-structure calculations by density functional theory (DFT) methods. The magnetoresistance and the Hall effect as well as the DFT results show that ferromagnetic Sn2Co3S2 is a compensated metal. The Sn-119 Mossbauer spectroscopic data confirm these findings. Large transferred hyperfine fields B-hf up to 34.2 T are observed.



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Details

Item typeArticle
Journal or Publication TitlePhysical Review B (PRB)
Publisher:AMER PHYSICAL SOC
Place of Publication:COLLEGE PK
Volume:88
Page Range:p. 144404
Date2013
InstitutionsChemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Richard Weihrich
Identification Number
ValueType
10.1103/PhysRevB.88.144404DOI
KeywordsSN; ANTIPEROVSKITES; CHALCOGENIDES; CO3SN2S2; SULFUR; PHASES; TIN; NI;
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-289323
Item ID28932

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