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Ferromagnetic ordering and half-metallic state of Sn2Co3S2 with the shandite-type structure
Schnelle, W., Leithe-Jasper, A., Rosner, H., Schappacher, F.M., Pöttgen, R., Pielnhofer, F.
and Weihrich, Richard
(2013)
Ferromagnetic ordering and half-metallic state of Sn2Co3S2 with the shandite-type structure.
Physical Review B (PRB) 88, p. 144404.
Date of publication of this fulltext: 18 Oct 2013 07:47
Article
DOI to cite this document: 10.5283/epub.28932
Abstract
Single crystalline Sn2Co3S2 with the shandite-type structure was investigated by magnetization, magnetoresistance, Hall effect, and heat capacity measurements and by Sn-119 Mossbauer spectroscopy. Sn2Co3S2 orders ferromagnetically at 172 K with an easy-axis magnetization of approximate to 1 mu(B) along the hexagonal c axis. The half-metallic ferromagnetic state is investigated by detailed ...
Single crystalline Sn2Co3S2 with the shandite-type structure was investigated by magnetization, magnetoresistance, Hall effect, and heat capacity measurements and by Sn-119 Mossbauer spectroscopy. Sn2Co3S2 orders ferromagnetically at 172 K with an easy-axis magnetization of approximate to 1 mu(B) along the hexagonal c axis. The half-metallic ferromagnetic state is investigated by detailed band-structure calculations by density functional theory (DFT) methods. The magnetoresistance and the Hall effect as well as the DFT results show that ferromagnetic Sn2Co3S2 is a compensated metal. The Sn-119 Mossbauer spectroscopic data confirm these findings. Large transferred hyperfine fields B-hf up to 34.2 T are observed.
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| Item type | Article | ||||
| Journal or Publication Title | Physical Review B (PRB) | ||||
| Publisher: | AMER PHYSICAL SOC | ||||
|---|---|---|---|---|---|
| Place of Publication: | COLLEGE PK | ||||
| Volume: | 88 | ||||
| Page Range: | p. 144404 | ||||
| Date | 2013 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Richard Weihrich | ||||
| Identification Number |
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| Keywords | SN; ANTIPEROVSKITES; CHALCOGENIDES; CO3SN2S2; SULFUR; PHASES; TIN; NI; | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-289323 | ||||
| Item ID | 28932 |
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