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Exceptionally High Felkin-Anh Control for the Addition of Nucleophiles to a β-Amino-cyclo-propylcarbaldehyde

Bubert, Christian ; Reiser, Oliver



Abstract

Exceptionally high diastereocontrol in agreement with the Felkin-Anh model was observed for the addition of nucleophiles to the β-aminocyclopropylcarbaldehyde 5 in nitroaldol, cyanohydrin, Mukaiyama aldol, and Sakurai reactions, contrasting the low diastereoselectivities generally observed in additions to cyclopropylcarbaldehydes.


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