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Unveiling the dual role of the cholinium hexanoate ionic liquid as solvent and catalyst in suberin depolymerisation

Ferreira, Rui ; Garcia, Helga ; Sousa, Andreia ; Guerreiro, Marina ; Duarte, Filipa ; Freire, Carmen ; Calhorda, Maria Jose ; Silvestre, Armando ; Kunz, Werner ; Rebelo, Luis ; Pereira, Cristina



Abstract

Disruption of the three-dimensional network of suberin in cork by cholinium hexanoate leads to its efficient and selective isolation. The reaction mechanism, which likely involves selective cleavage of some inter-monomeric bonds in suberin, was still unanswered. To address this question, the role of the ionic liq. during suberin depolymn. and during cleavage of std. compds. carrying key chem. ...

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