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Half Antiperovskites VI: On the Substitution Effects in Shandites InxSn2–xCo3S2

Pielnhofer, F. ; Rothballer, J. ; Peter, Ph. ; Yan, W. ; Schappacher, F.M. ; Pöttgen, R. ; Weihrich, Richard



Abstract

In the shandite type solid solution InxSn2–xCo3S2 the transition from half metal ferromagnetic Sn2Co3S2 to the new thermoelectric InSnCo3S2 is related to A = In, Sn on different crystallographic sites. Effects and origin of crystal and electronic structure changes induced by A = In are now investigated within the solid solution 0 ≤ x ≤ 2 including In2Co3S2. Effects are studied from X-ray data, ...

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