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Half Antiperovskites VI: On the Substitution Effects in Shandites InxSn2–xCo3S2

Pielnhofer, F., Rothballer, J., Peter, Ph., Yan, W., Schappacher, F.M., Pöttgen, R. and Weihrich, Richard (2014) Half Antiperovskites VI: On the Substitution Effects in Shandites InxSn2–xCo3S2. Z. Anorg. Allg. Chem. 640 (2), pp. 286-294.

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In the shandite type solid solution InxSn2–xCo3S2 the transition from half metal ferromagnetic Sn2Co3S2 to the new thermoelectric InSnCo3S2 is related to A = In, Sn on different crystallographic sites. Effects and origin of crystal and electronic structure changes induced by A = In are now investigated within the solid solution 0 ≤ x ≤ 2 including In2Co3S2. Effects are studied from X-ray data, ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Richard Weihrich
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Keywords:Structure property relations; Shandite; Mößbauer spectroscopy; Electric field gradients; Density functional calculations; Sn2Co3S2
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:29610
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