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Elongated Gilman Cuprates: The Key to Different Reactivities of Cyano- and Iodocuprates

Neumeier, M. ; Gschwind, R. M.


In the past the long-standing and very controversial discussion about a special reactivity of cyano- versus iodocuprates concentrated on the existence of higher-order cuprate structures. Later on numerous structural investigations proved the structural equivalence of iodo and cyano Gilman cuprates and their subsequential intermediates. For dimethylcuprates similar reactivities were also shown. ...


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