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Cs5Sn9(OH)x4 NH3

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Friedrich, Ute ; Korber, Nikolaus
License: Creative Commons: Attribution 3.0
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Date of publication of this fulltext: 29 Jul 2014 08:54


The title compound, penta­caesium nona­stannide hydroxide tetra­ammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn94- unit forms a monocapped quadratic anti­prism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A three-dimensional network is formed by Cs-Sn [3.8881 (7) Å to 4.5284 (7) Å] and Cs-NH3 [3.276 (7)-3.636 (7) Å] contacts.

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