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- urn:nbn:de:bvb:355-epub-304799
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Abstract
The title compound, pentacaesium nonastannide hydroxide tetraammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn94- unit forms a monocapped quadratic antiprism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A three-dimensional network is formed by Cs-Sn [3.8881 (7) Å to 4.5284 (7) Å] and Cs-NH3 [3.276 (7)-3.636 (7) Å] contacts.
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