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(18-Crown-6)potassium(I) diphenylstibate(-1)

URN to cite this document:
urn:nbn:de:bvb:355-epub-304856
Kaas, Marina ; Friedrich, Ute ; Korber, Nikolaus
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Date of publication of this fulltext: 29 Jul 2014 12:44


Abstract

Red crystals of the title salt, [K(C12H24O6)][Sb(C6H5)2], were obtained by the reaction of SbPh3, KSnBi and 18-crown-6 in liquid ammonia. The asymmetric unit contains one half of a [K(18-crown-6)]+ cation and one half of an SbPh2- anion, with the central element lying on a twofold axis and a centre of inversion, respectively. In the crystal structure, the sequestered potassium cations show weak ...

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