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Parallel Kinetic Resolution of Racemic Aldehydes by Use of Asymmetric Horner-Wadsworth-Emmons Reactions

Pedersen, Torben M. ; Jensen, Jakob F. ; Humble, Rikke E. ; Rein, Tobias ; Tanner, David ; Bodmann, Kerstin ; Reiser, Oliver



Abstract

A racemic aldehyde can undergo parallel kinetic resolution (PKR) by simultaneous reaction with two different chiral phosphonates, differing either in the structure of the chiral auxiliary or in the structure of the phosphoryl group (i.e., one (E)- and one (Z)-selective reagent). This strategy allows conversion of a racemic aldehyde to two different, synthetically useful chiral products with ...

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