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Origin and effect of In–Sn ordering in InSnCo3S2: a neutron diffraction and DFT study

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Rothballer, Jan ; Bachhuber, Frederik ; Rommel, S. ; Soehnel, Tilo ; Weihrich, Richard
License: Creative Commons: Attribution 3.0
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Date of publication of this fulltext: 30 Sep 2014 12:24


The solid solution In2−xSnxCo3S2 is attractive due to a variety of interesting properties depending on the In/Sn content, i.e. half metal ferromagnetic Sn2Co3S2, low dimensional metal In2Co3S2, and semiconducting thermoelectric InSnCo3S2. For the latter, crystal structure effects and a metal to insulator transition are not only related to electron counting but also to ordering of In and Sn within ...


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