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Polynuclear Phosphoramidite Copper Complexes with Mixed Trigonal/Tetrahedral Coordination in THF

von Rekowski, Felicitas ; Gschwind, Ruth Maria



Abstract

In the field of asymmetric copper-catalyzed 1,4-addition reactions new applications were established using triorganoaluminum reagents in etheral solvents. This raised the question of whether phosphoramidite copper complexes have similar structures and aggregation levels in THF compared to noncoordinating solvents such as CD2Cl2. Therefore, NMR spectroscopic investigations of the precatalytic ...

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