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About the polymorphism of Li(C${\sb 4}$H${\sb 8}$O)${\sb 3}$I: crystal structures of trigonal and tetragonal polymorphs

URN to cite this document:
urn:nbn:de:bvb:355-epub-310434
Gärtner, Stefanie ; Gärtner, Tobias ; Gschwind, Ruth-Maria ; Korber, Nikolaus
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Date of publication of this fulltext: 16 Dec 2014 16:45


Abstract

Two new trigonal and tetra­gonal polymorphs of the title compound, iodido­tris­(tetra­hydro­furan-[kappa]O)lithium, are presented, which both include the isolated ion pair Li(THF)3+·I-. One Li-I ion contact and three tetra­hydro­furan (THF) mol­ecules complete the tetra­hedral coordination of the lithium cation. The three-dimensional arrangement in the two polymorphs differs notably. In the ...

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