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Nitrogen(II) Oxide Charge Transfer Complexes on TiO2: A New Source for Visible-Light Activity

Freitag, J. ; Dominguez, A. ; Niehaus, Thomas A. ; Huelsewig, A. ; Dillert, R. ; Frauenheim, T. ; Bahnemann, D. W.


A combined experimental and computational study of the photocatalytic activity of titanium dioxide (TiO2) for the degradation of nitrogen(II) oxide (NO) and acetaldehyde is reported. We employ five different TiO2 photocatalysts including pure anatase and rutile samples. The experimental photonic efficiencies indicate that, under visible irradiation, the samples containing pure TiO2 are active for ...


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