Stereoselective iron-catalyzed alkyne hydrogenation in ionic liquids

URN to cite this document:: urn:nbn:de:bvb:355-epub-316627

Gieshoff, Tim N. ; Welther, Alice ; Kessler, Michael T. ; Prechtl, Martin H. G. ; Jacobi von Wangelin, Axel

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Date of publication of this fulltext: 20 Apr 2015 13:06

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Abstract

Iron(0) nanoparticles in ionic liquids (ILs) have been shown to catalyse the semi-hydrogenation of alkynes. In the presence of a nitrile-functionalised IL or acetonitrile, stereoselective formation of (Z)-alkenes was observed. The biphasic solvent system allowed facile separation and re-use of the catalyst.

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