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High-Pressure Induced Domino-Horner-Wadsworth-Emmons (HWE) -Michael Reactions

Has-Becker, Senay ; Bodmann, Kerstin ; Kreuder, Reinhard ; Santoni, Gabriella ; Rein, Tobias ; Reiser, Oliver



Abstract

A new protocol for the alkenylation of carbonyl compounds with phosphonates (Horner-Wadsworth-Emmons reaction) is described. Aldehydes react with phosphonates already at room temperature in the presence of triethylamine without further activation by Lewis-acids if high-pressure (8 kbar) is applied to the system. Based on this protocol a domino process was developed combining the HWE reaction with ...

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