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The interface makes a difference: lanthanide ion coated vesicles hydrolyze phosphodiesters

Poznik, Michal, Maitra, Uday and König, Burkhard (2015) The interface makes a difference: lanthanide ion coated vesicles hydrolyze phosphodiesters. Organic & Biomolecular Chemistry 13, pp. 9789-9792.

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Lanthanide ions are strong Lewis acids. Their complexation to a variety of ligands can further enhance their Lewis acidity allowing the hydrolysis of phosphoesters and even DNA. We show that the interaction of lanthanide ions with vesicles from zwitterionic phosphatidylcholine lipids gives supramolecular structures in which the metal ion is loosely coordinated to the surface. This assembly ...


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Item type:Article
Date:31 July 2015
Additional Information (public):Open Access Komponente aus der Allianzlizenz
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:32355
Owner only: item control page


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