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Stability and Conversion of Tin Zintl Anions in Liquid Ammonia Investigated by NMR Spectroscopy

Fendt, Franziska, Koch, Carina, Neumeier, Maria, Gärtner, Stefanie, Gschwind, Ruth Maria and Korber, Nikolaus (2015) Stability and Conversion of Tin Zintl Anions in Liquid Ammonia Investigated by NMR Spectroscopy. Chem. Eur. J. 21 (41), pp. 14539-14544.

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Abstract

Homoatomic polyanions of post-transition main-group metals, namely, Zintl anions, are precast in analogous Zintl phases and can react in solution to form new materials. Despite comprehensible reaction approaches, the formed products cannot be planned in advance, as hitherto undetected and therefore disregarded side reactions take place. The outcomes and interpretations of the reactions of Zintl ...

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Item type:Article
Date:2015
Additional Information (public):Early View (Online Version of Record published before inclusion in an issue)
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/chem.201501100DOI
Keywords:alkali metals cryptands NMR spectroscopy tin Zintl anions
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:32378
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