Go to content
UR Home

Halocuprate(I) Zigzag Chain Structures with N-Methylated DABCO Cations – Bright Metal-Centered Luminescence and Thermally Activated Color Shifts

Maderlehner, Sebastian, Leitl, Markus J., Yersin, Hartmut and Pfitzner, Arno (2015) Halocuprate(I) Zigzag Chain Structures with N-Methylated DABCO Cations – Bright Metal-Centered Luminescence and Thermally Activated Color Shifts. Dalton Transactions 44, pp. 19305-19313.

[img]
Preview
PDF - Published Version
Download (1MB)
[img]
Preview
PDF
Download (1MB)
Date of publication of this fulltext: 16 Nov 2015 08:45

at publisher (via DOI)


Abstract

Two compounds 1,4-dimethyl-1,4-diazoniabicyclo[2.2.2]octane catena-tetra-μ-halo-dicuprate(I) with DABCOMe2 Cu2X4 (1: X = Br, 2: X = I) were synthesized by hydrothermal reaction of copper(I) halides with the corresponding 1,4-diazoniabicyclo[2.2.2]octane (DABCO) dihydrohalides in an acetonitrile/methanol mixture. Both compounds crystallize monoclinically, 1 with a = 9.169(4) Å, b = 10.916(6) Å, c ...

plus


Export bibliographical data



Item type:Article
Date:2015
Additional Information (public):Open Access Komponente aus der Allianzlizenz
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1039/C5DT02709HDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:32791
Owner only: item control page

Downloads

Downloads per month over past year

  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons