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Halocuprate(I) Zigzag Chain Structures with N-Methylated DABCO Cations – Bright Metal-Centered Luminescence and Thermally Activated Color Shifts

URN to cite this document:
urn:nbn:de:bvb:355-epub-327911
DOI to cite this document:
10.5283/epub.32791
Maderlehner, Sebastian ; Leitl, Markus J. ; Yersin, Hartmut ; Pfitzner, Arno
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Date of publication of this fulltext: 16 Nov 2015 08:45



Abstract

Two compounds 1,4-dimethyl-1,4-diazoniabicyclo[2.2.2]octane catena-tetra-μ-halo-dicuprate(I) with DABCOMe2 Cu2X4 (1: X = Br, 2: X = I) were synthesized by hydrothermal reaction of copper(I) halides with the corresponding 1,4-diazoniabicyclo[2.2.2]octane (DABCO) dihydrohalides in an acetonitrile/methanol mixture. Both compounds crystallize monoclinically, 1 with a = 9.169(4) Å, b = 10.916(6) Å, c ...

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