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Immobilisation of bis(oxazoline)-copper complexes on clays and nanocomposites. Influence of different parameters on activity and selectivity

Fraile, Jose M. ; Garcia, Jose I. ; Harmer, Mark A. ; Herrerías, Clara I. ; Mayoral, Jose A. ; Reiser, Oliver ; Werner, Heiko


Bis(oxazoline)–copper complexes, immobilised by electrostatic interactions on Laponite and Nafion/silica nanocomposites, have been tested as catalysts in the cyclopropanation of styrene with ethyl diazoacetate. Several factors play a decisive role in the outcome of the reaction. Firstly, the nature of the solid counterion is important, with perfluorosulfonic solids being the best in this regard. ...


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