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Immobilisation of Water‐oxidising Amphiphilic Ruthenium Complexes on Unmodified Silica Gel

Králík, Antonin ; Hansen, Malte ; König, Burkhard



Abstract

Amphiphilic ruthenium complexes that catalyse the oxidation of water by light or cerium(IV) are non‐covalently immobilised on untreated, commercial silica gel. The heterogeneous catalysts are prepared easily in one step and require no additives. High affinity of the amphiphilic complexes to silica gel leads to their rapid absorption from chloroform solution on silica gel. The complexes maintain ...

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