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A new class of deep-blue emitting Cu(I) compounds – effects of counter ions on the emission behavior

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Gneuß, Timo ; Leitl, Markus J. ; Finger, Lars H. ; Yersin, Hartmut ; Sundermeyer, Jörg
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Date of publication of this fulltext: 12 Feb 2016 11:08


Three deep blue emitting Cu(I) compounds, [Cu(PPh3)tpym]PF6, [Cu(PPh3)tpym]BF4, and [Cu(PPh3)tpym]BPh4 (tpym = tris(2-pyridyl)methane, PPh3 = triphenylphosphine) featuring the tripodally coordinating tpym and the monodentate PPh3 ligands were studied with regard to their structural and photophysical properties. The compounds only differ in their respective counter ions which have a strong impact ...


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