The approach to 4d/4f-polyphosphides

URN to cite this document:: urn:nbn:de:bvb:355-epub-333056
DOI to cite this document:: 10.5283/epub.33305

Arleth, Nicholas ; Gamer, Michael T. ; Köppe, Ralf ; Pushkarevsky, Nikolay A.

; Konchenko, Sergey N. ; Fleischmann, Martin ; Bodensteiner, Michael ; Scheer, Manfred

; Roesky, Peter W.

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Date of publication of this fulltext: 16 Feb 2016 09:58

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Abstract

The first 4d/4f polyphosphides were obtained by reaction of the divalentmetallocenes [Cp*(2)Ln(thf)(2)] (Ln = Sm, Yb) with [{CpMo(CO)(2)}(2)(mu,eta(2:2)-P-2)] or [Cp*Mo(CO)(2)(eta(3)-P-3)]. Treatment of [Cp*(2)Ln(thf)(2)] (Ln = Sm, Yb) with [{CpMo(CO)(2)}(2)(mu,eta(2:2)-P-2)] gave the 16-membered bicyclic compounds [(Cp-2*L-n)(2)P-2(CpMo(CO)(2))(4)] (Ln = Sm, Yb) as the major products. From the ...