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The approach to 4d/4f-polyphosphides

Arleth, Nicholas, Gamer, Michael T., Köppe, Ralf, Pushkarevsky, Nikolay A., Konchenko, Sergey N., Fleischmann, Martin, Bodensteiner, Michael, Scheer, Manfred and Roesky, Peter W. (2015) The approach to 4d/4f-polyphosphides. Chemical Science (Chem. Sci.) 6, pp. 7179-7184.

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Abstract

The first 4d/4f polyphosphides were obtained by reaction of the divalent metallocenes [Cp*2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] or [Cp*Mo(CO)2(η3-P3)]. Treatment of [Cp*2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] gave the 16-membered bicyclic compounds [(Cp2*Ln)2P2(CpMo(CO)2)4] (Ln = Sm, Yb) as the major products. From the reaction involving samarocene, the cyclic P4 ...

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Item type:Article
Date:2015
Additional Information (public):Open Access Komponente aus der Allianzlizenz
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/c5sc02252eDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33305
Owner only: item control page

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