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The synthesis of the heterocubane cluster [{CpMn}₄(µ₃-P)₄] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds

Heinl, Sebastian, Kiefer, Konrad, Balázs, Gábor, Wickleder, Claudia and Scheer, Manfred (2015) The synthesis of the heterocubane cluster [{CpMn}₄(µ₃-P)₄] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds. Chemical Communications (Chem. Commun.) 51, pp. 13474-13477.

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Abstract

Thermolysis of [CpMn(η⁶-cht)] with P₄ in 1,3-diisopropylbenzene leads to the formation of the heterocubane [Cp₄Mn₄P₄] (1) in high yields, as a rare example of ‘naked’ phosphorus containing complexes of manganese. Compound 1 is characterized and studied by DFT calculations and reflection measurements. 1D coordination polymers [{(CpMn)₄(μ₃-P)₄}(CuX)]n (2-Cl: X = Cl; 2-Br: X = Br) are obtained in ...

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Item type:Article
Date:2015
Additional Information (public):Open Access Komponente aus der Allianzlizenz
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number:
ValueType
10.1039/C5CC04800ADOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33311
Owner only: item control page

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