The synthesis of the heterocubane cluster [{CpMn}₄(µ₃-P)₄] as a tetrahedral shaped starting material for the formation of polymeric coordination compounds

URN to cite this document:: urn:nbn:de:bvb:355-epub-333113
DOI to cite this document:: 10.5283/epub.33311

Heinl, Sebastian ; Kiefer, Konrad ; Balázs, Gábor ; Wickleder, Claudia ; Scheer, Manfred

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Date of publication of this fulltext: 19 Feb 2016 13:24

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Abstract

Thermolysis of [CpMn(η⁶-cht)] with P₄ in 1,3-diisopropylbenzene leads to the formation of the heterocubane [Cp₄Mn₄P₄] (1) in high yields, as a rare example of ‘naked’ phosphorus containing complexes of manganese. Compound 1 is characterized and studied by DFT calculations and reflection measurements. 1D coordination polymers [{(CpMn)₄(μ₃-P)₄}(CuX)]n (2-Cl: X = Cl; 2-Br: X = Br) are obtained in ...