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Enantioselective Synthesis of Paraconic Acids

Chhor, Rakeshwar B. ; Nosse, Bernd ; Sörgel, Sebastian ; Böhm, Claudius ; Seitz, Michael ; Reiser, Oliver


The development of a new method for the enantioselective synthesis of disubstituted -butyrolactones is reported. Based on this strategy, the total synthesis of three paraconic acids, that is (-)-roccellaric acid, (-)-nephrosteranic acid and (-)-protopraesorediosic acid, and the formal total synthesis of (-)-methylenolactocin and (-)-protolichesterinic acid is described, which are important ...


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