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Visible light amination/Smiles cascade: access to
phthalazine derivatives

Brachet, Etienne, Marzo, Leyre, Selkti, Mohamed, König, Burkhard and Belmont, Philippe (2016) Visible light amination/Smiles cascade: access to
phthalazine derivatives.
Chemical Science 7, pp. 5002-5006.

License: Creative Commons Attribution Non-commercial 3.0
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Date of publication of this fulltext: 01 Jun 2016 07:48

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We report the synthesis of various phthalazines via a new cascade reaction, initiated by visible light photocatalysis, involving a radical hydroamination reaction followed by a radical Smiles rearrangement. Phthalazine derivatives are obtained in high yields and from a broad scope readily accessible orthoalkynylsulfonohydrazone precursors. The mild photoredox conditions ensure an excellent ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:33842
Owner only: item control page


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