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Syntheses, crystal structures, reactivity, and photochemistry of gold(III) bromides bearing N-heterocyclic carbenes

Hirtenlehner, C., Krims, C., Hölbling, J., List, M. and Zabel, Manfred (2011) Syntheses, crystal structures, reactivity, and photochemistry of gold(III) bromides bearing N-heterocyclic carbenes. Dalton Transactions 40, pp. 9899-9910.

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Abstract

Gold(I) complexes bearing N-heterocyclic carbenes (NHC) of the type (NHC)AuBr (3a/3b) [NHC = 1-methyl-3-benzylimidazol-2-ylidene (= MeBnIm), and 1,3-dibenzylimidazol-2-ylidene (= Bn2Im)] are prepared by transmetallation reactions of (tht)AuBr (tht = tetrahydrothiophene) and (NHC)AgBr (2a/2b). The homoleptic, ionic complexes [(NHC)2Au]Br (6a/6b) are synthesized by the reaction with free carbene. ...

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Item type:Article
Date:2011
Institutions:UNSPECIFIED
Identification Number:
ValueType
10.1039/C1DT11175BDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34122
Owner only: item control page

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