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Control of metal-directed self-assembly by metal–amine interactions

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Katayev, E. ; Schmid, Markus B.
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 22 Jul 2016 12:54


The complexation of a tweezers ligand with zinc perchlorate in the absence and presence of amines in methanol solution was explored. L2Zn2(ClO4)4 was a thermodynamic product of the reaction in the absence of an amine. The complex was shown to interact with aliphatic amines resulting in the formation of a Zn–N(amine) bond. If metal–ligand complexation was carried out in the presence of an amine ...


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