Geiger, Christian, Kreitmeier, Peter and Reiser, Oliver (2005) Cobalt(II)-Azabis(oxazoline)-Catalyzed Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds. Advanced Synthesis & Catalysis 347 (2-3), pp. 249-254.
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Other URL: http://dx.doi.org/10.1002/adsc.200404295
Abstract
Azabis(oxazolines) prove to be superior ligands for the enantioselective, cobalt(II)-catalyzed conjugate reduction of α,β-unsaturated carbonyl compounds with sodium borohydride. β-Trisubstituted α,β-unsaturated esters and amides as well as γ-butenolides are readily converted to their corresponding saturated counterparts with enantioselectivities up to 97% ee.
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 14 February 2005 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser | ||||
| Identification Number: |
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| Keywords: | azabis(oxazolines); cobalt; conjugate reduction; transition metals; α,β-unsaturated amides; α,β-unsaturated esters | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Item ID: | 343 |
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