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Riechers, Alexander ; Pentlehner, D. ; Slenczka, Alkwin

Microsolvation in superfluid helium droplets studied by the electronic spectra of six porphyrin derivatives and one chlorine compound

Riechers, Alexander, Pentlehner, D. und Slenczka, Alkwin (2013) Microsolvation in superfluid helium droplets studied by the electronic spectra of six porphyrin derivatives and one chlorine compound. The Journal of Chemical Physics 138, S. 244303.

Veröffentlichungsdatum dieses Volltextes: 20 Okt 2016 11:10
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.34739


Zusammenfassung

After almost two decades of high resolution molecular spectroscopy in superfluid helium droplets, the understanding of microsolvation is still the subject of intense experimental and theoretical research. According to the published spectroscopic work including microwave, infrared, and electronic spectroscopy, the latter appears to be particularly promising to study microsolvation because of the ...

After almost two decades of high resolution molecular spectroscopy in superfluid helium droplets, the understanding of microsolvation is still the subject of intense experimental and theoretical research. According to the published spectroscopic work including microwave, infrared, and electronic spectroscopy, the latter appears to be particularly promising to study microsolvation because of the appearance of pure molecular transitions and spectrally separated phonon wings. Instead of studying the very details of the influence of the helium environment for one particular dopant molecule as previously done for phthalocyanine, the present study compares electronic spectra of a series of non-polar porphyrin derivatives when doped into helium droplets consisting of 10(4)-10(5) helium atoms. Thereby, we focus on the helium-induced fine structure, as revealed most clearly at the corresponding electronic origin. The interpretation and the assignment of particular features obtained in the fluorescence excitation spectra are based on additional investigations of dispersed emission spectra and of the saturation behavior. Besides many dopant-specific results, the experimental study provides strong evidence for a particular triple peak feature representing the characteristic signature of helium solvation for all seven related dopant species. (C) 2013 AIP Publishing LLC.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftThe Journal of Chemical Physics
Verlag:AMER INST PHYSICS
Ort der Veröffentlichung:MELVILLE
Band:138
Seitenbereich:S. 244303
Datum2013
InstitutionenChemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Lehrstuhl für Physikalische Chemie I > Prof. Dr. Alkwin Slenzka
Identifikationsnummer
WertTyp
10.1063/1.4811199DOI
Stichwörter / KeywordsISOLATED ULTRACOLD PORPHYRINS; LIQUID-HELIUM; SUPERSONIC EXPANSIONS; HE-4 DROPLETS; SPECTROSCOPY; TETRACENE; MOLECULES; NANODROPLETS; CLUSTERS; PHTHALOCYANINE;
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-347395
Dokumenten-ID34739

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