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Stereoselective synthesis of novel conformationally restricted β- and γ-amino acids

Gnad, Frieder ; Poleschak, Marko ; Reiser, Oliver



Abstract

Novel conformationally restricted β- and γ-amino acids containing a cyclopropane ring could be stereoselectively synthesized from readily available 5-methoxyindole and pyridine by copper(I)-catalyzed cyclopropanation with methyl diazoacetate followed by subsequent oxidative cleavage of the resulting adducts.


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