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Photocatalytic activation of N-chloro compounds for the
chlorination of arenes

Hering, Thea and König, Burkhard (2016) Photocatalytic activation of N-chloro compounds for the
chlorination of arenes.
Tetrahedron 72, pp. 7821-7825.

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Abstract

Photoredox catalysis activates N-chloramines and N-chloro-succinimide (NCS) for the electrophilic chlorination of arenes. The photooxidation of the nitrogen atom to a radical cation induces a positive polarization on the chlorine atom, which results in a higher reactivity in electrophilic aromatic chlorination reactions.


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Item type:Article
Date:2016
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1016/j.tet.2016.06.028DOI
Keywords:Photocatalysis, Electron transfer, Electrophilic chlorination
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34832
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