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The role of binding constant in the efficiency of chiral catalysts immobilized by electrostatic interactions. The case of azabis(oxazoline)-copper complexes

Fraile, José M. ; García, José I. ; Herrerías, Clara I. ; Mayoral, José A. ; Reiser, Oliver ; Socuéllamos, Antonio ; Werner, Heiko


As shown by theoretical calculations, azabis(oxazoline)-copper complexes are considerably more stable than the analogous bis(oxazoline)-copper complexes. This enhanced stability allows them to be efficiently immobilized by means of electrostatic interactions to different anionic supports, such as clays and nafion-silica nanocomposites, without the loss of a ligand, as is observed for ...


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