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Helical, non-racemic inorganic-organic hybrid polymers of cadmium halides with pentadentate bis(oxazoline) ligands

Seitz, Michael ; Kaiser, Anja ; Stempfhuber, Sabine ; Zabel, Manfred ; Reiser, Oliver



Abstract

A chiral, nonracemic pentadentate pyridine bis(oxazoline) ligand forms unprecedented P-helical inorganic-organic hybrid polymers with cadmium halides. The one-dimensional chains consist of 2-configured pentagonal-bipyramidal cadmium complexes with metal-centered chirality bridged by [CdX4]2- tetrahedra via shared halide atoms. In the solid state, the overall helicity exhibits strongly directed orientation parallel to the crystallographic axis a.


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