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Hydration and self-​aggregation of a neutral cosolute from dielectric relaxation spectroscopy and MD simulations: the case of 1,​3-​dimethylurea

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Agieienko, Vira ; Buchner, Richard ; Horinek, Dominik
License: Creative Commons: Attribution 3.0
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Date of publication of this fulltext: 14 Mar 2017 07:31


The influence of the amphiphile 1,3-dimethylurea (1,3-DMU) on the dynamic properties of water was studied using dielec. relaxation spectroscopy. The expt. provided evidence for substantial retardation of water reorientation in the hydration shell of 1,3-DMU, leading to a sep. slow-water relaxation in addn. to contributions from bulk-like and fast water as well as from the solute. From the ...


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