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Dielectric relaxation of nitromethane and its mixtures with ethylammonium nitrate: Evidence for strong ion association induced by hydrogen bonding

Nazet, Andreas ; Weiß, Lisa ; Buchner, Richard



Abstract

Binary mixtures of the aprotic protophobic solvent nitromethane (NM) and the protic room-temperature ionic liquid ethylammonium nitrate (EAN) were studied with dielectric relaxation spectroscopy in the two single-phase regions, 0 < chi(EAN) <= 0.013 and 0.4 <= chi(EAN) < 1, of the binary mixtures at 25 degrees C. All spectra were well described by a superposition of two relaxation processes whose ...

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