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Brønsted Acid Catalysis—Structural Preferences and Mobility in Imine/Phosphoric Acid Complexes

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Greindl, J. ; Hioe, J. ; Sorgenfrei, N. ; Morana, F. ; Gschwind, R. M.
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Date of publication of this fulltext: 16 Mar 2017 08:27


Despite the huge success of enantioselective Bronsted acid catalysis, experimental data about structures and activation modes of substrate/catalyst complexes in solution are very rare. Here, for the first time, detailed insights into the structures of imine/Bronsted acid catalyst complexes are presented on the basis of NMR data and underpinned by theoretical calculations. The chiral Bronsted acid ...


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