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Decarboxylative Alkynylation of Biomass-Derived Compounds by Metal-Free Visible Light Photocatalysis

Schwarz, Johanna and König, Burkhard (2017) Decarboxylative Alkynylation of Biomass-Derived Compounds by Metal-Free Visible Light Photocatalysis. ChemPhotoChem, pp. 237-242.

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Abstract

We report a mild method for the decarboxylative C-C bond formation between natural carboxylic acids and alkynes. Activation of a very broad scope of carboxylic acids derived from renewable resources is achieved by esterification to N (acyloxy)phthalimides. The cross coupling with acetylenic sulfones proceeds under irradiation with green light (528 nm) in the presence of the organic photocatalyst ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1002/cptc.201700034DOI
Keywords:decarboxylation • alkynylation • metal-free • photocatalytic • biomass
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:35437
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