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Direct C-H Phosphonylation of Electron Rich Arenes and Heteroarenes by Visible-Light Photoredox Catalysis

Shaikh, Rizwan, Ghosh, Indrajit and König, Burkhard (2017) Direct C-H Phosphonylation of Electron Rich Arenes and Heteroarenes by Visible-Light Photoredox Catalysis. Chemistry - A European Journal 23, pp. 12120-12124.

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Abstract

The direct transformation of ubiquitous, but chemically inert C-H bonds into diverse functional groups is an important strategy in organic synthesis that improves the atom economy and faclitates the preparation and modification of complex molecules. In contrast to the wide applications of aryl phosphonates, their synthesis via direct C-H bond phosphonylation is a less explored area. We report ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1002/chem.201701283DOI
Keywords:P BOND FORMATION; DIALKYL PHOSPHITES; ARYLBORONIC ACIDS; PHOSPHONATE DIESTERS; AROMATIC-COMPOUNDS; COUPLING REACTIONS; ROOM-TEMPERATURE; METAL-COMPLEXES; VINYL HALIDES; ARYL; C-H activation; late-stage functionalization; phosphonylation; photoredox catalysis; triethyl phosphite
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:35506
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