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Crystal structure of rubidium methyl­diazo­tate

Korber, Nikolaus and Grassl, Tobias (2017) Crystal structure of rubidium methyl­diazo­tate. Acta Crystallographica Section E 73 (2), pp. 159-161.

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Date of publication of this fulltext: 04 Sep 2017 08:52

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Abstract

The title compound, Rb+·H3CN2O-, has been crystallized in liquid ammonia as a reaction product of the reductive ammonolysis of the natural compound streptozocin. Elemental rubidium was used as reduction agent as it is soluble in liquid ammonia, forming a blue solution. Reductive bond cleavage in biogenic materials under kinetically controlled conditions offers a new approach to gain access to ...

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Item type:Article
Date:February 2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Projects:Open Access Publizieren (DFG)
Identification Number:
ValueType
10.1107/S2056989016020429DOI
Keywords:crystal structure; reductive ammonolysis; streptozocin; rubidium cation; methyl­diazo­tate anion.
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:35647
Owner only: item control page

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