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Sensitization-Initiated Electron Transfer for Photoredox Catalysis

Ghosh, Indrajit ; Shaikh, Rizwan ; König, Burkhard



Abstract

Photosynthetic organisms exploit antenna chromophores to absorb light and transfer excitation energy to the reaction center where redox reactions occur. In contrast, in visible-light chemical photoredox catalysis, a single species (i.e., the photoredox catalyst) absorbs light and performs the redox chemistry. Mimicking the energy flow of the biological model, we report a two-center photoredox ...

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