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Sensitization-Initiated Electron Transfer for Photoredox Catalysis

Ghosh, Indrajit , Shaikh, Rizwan and König, Burkhard (2017) Sensitization-Initiated Electron Transfer for Photoredox Catalysis. Angewandte Chemie International Edition 56, pp. 8544-8549.

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Abstract

Photosynthetic organisms exploit antenna chromophores to absorb light and transfer excitation energy to the reaction center where redox reactions occur. In contrast, in visible-light chemical photoredox catalysis, a single species (i.e., the photoredox catalyst) absorbs light and performs the redox chemistry. Mimicking the energy flow of the biological model, we report a two-center photoredox ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1002/ange.201703004DOI
10.1002/anie.201703004DOI
Keywords:ENERGY-TRANSFER; LIGHT; SUBSTITUTION; TRANSITION; REDUCTION; ARYLATION; COMPLEXES; IODIDES; C-H arylation; electron transfer; energy transfer; photocatalysis; polycyclic aromatic hydrocarbons
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:35755
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