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Polymorphism of CsGaS2 – Structural Characterization of a new two-dimensional Polymorph and Study of the Phase-Transition Kinetics

URN to cite this document:
urn:nbn:de:bvb:355-epub-358024
DOI to cite this document:
10.5283/epub.35802
Friedrich, D. ; Schlosser, Marc ; Weihrich, Richard ; Pfitzner, Arno
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Date of publication of this fulltext: 06 Jul 2017 06:02


Abstract

CsGaS2-mC64 was obtained by reaction of CsN3 with stoichiometric amounts of Ga2S3 and S at elevated temperatures. The crystal structure of the air- and moisture stable compound was determined from single-crystal X-ray diffraction data. The colourless solid crystallizes in the monoclinic space group C2/c (no. 15) with the lattice parameters a = 10.5718(6) angstrom, b = 10.5708(6) angstrom, c = ...

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