Polymorphism of CsGaS2 – Structural Characterization of a new two-dimensional Polymorph and Study of the Phase-Transition Kinetics - University of Regensburg Publication Server

URN to cite this document:: urn:nbn:de:bvb:355-epub-358024
DOI to cite this document:: 10.5283/epub.35802

Friedrich, D.

; Schlosser, Marc

; Weihrich, Richard ; Pfitzner, Arno

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Date of publication of this fulltext: 06 Jul 2017 06:02

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Abstract

CsGaS2-mC64 was obtained by reaction of CsN3 with stoichiometric amounts of Ga2S3 and S at elevated temperatures. The crystal structure of the air- and moisture stable compound was determined from single-crystal X-ray diffraction data. The colourless solid crystallizes in the monoclinic space group C2/c (no. 15) with the lattice parameters a = 10.5718(6) angstrom, b = 10.5708(6) angstrom, c = ...