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Interconversion of one-dimensional Thiogallates Cs2[Ga2(S2)2-xS2+x] (x = 0, 1, 2) by using high-temperature Decomposition and Polysulfide-Flux Reactions

Friedrich, Daniel , Schlosser, Marc and Pfitzner, Arno (2017) Interconversion of one-dimensional Thiogallates Cs2[Ga2(S2)2-xS2+x] (x = 0, 1, 2) by using high-temperature Decomposition and Polysulfide-Flux Reactions. Cryst. Growth & Design 17 (9), pp. 4887-4892.

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Date of publication of this fulltext: 28 Nov 2017 11:19

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Abstract

The potential of cesium polysulfide-flux reactions for the synthesis of chalcogenogallates was investigated by using X-ray diffraction and Raman spectroscopy. An investigation of possible factors influencing the product formation revealed that only the polysulfide content x in the Cs2Sx melts has an influence on the crystalline reaction product. From sulfur-rich melts (x > 7), CsGaS3 is formed, ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Identification Number:
ValueType
10.1021/acs.cgd.7b00840DOI
Keywords:STRUCTURAL-CHARACTERIZATION; METAL POLYCHALCOGENIDES; CRYSTAL-STRUCTURES; COMPOUND; ANIONS;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:36359
Owner only: item control page

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