Go to content
UR Home

The effect of alkyl-​chain branching on the hydration and ion association of tetrabutylammonium cations

Moreno-Gomez, Nicolas, Vargas, Edgar F. and Buchner, Richard (2017) The effect of alkyl-​chain branching on the hydration and ion association of tetrabutylammonium cations. Journal of Molecular Liquids 248, pp. 586-594.

Full text not available from this repository.

at publisher (via DOI)


Abstract

Association constants and single-ion conductivities of the bromide salts of five isomeric tetrabutylammonium ions were determined with dilute-solution conductivity measurements for aqueous solutions at 298.15 K. In addition, for two of the isomers dielectric relaxation experiments were performed. It was found that, despite similar size of all cations, the hydrodynamic radii of the branched ...

plus


Export bibliographical data



Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1016/j.molliq.2017.09.123DOI
Keywords:QUATERNARY AMMONIUM-COMPOUNDS; DIELECTRIC-RELAXATION SPECTROSCOPY; AQUEOUS-SOLUTIONS; HYDROPHOBIC HYDRATION; ELECTROLYTE-SOLUTIONS; TETRAALKYLAMMONIUM HALIDES; NEUTRON-SCATTERING; WATER MIXTURES; DYNAMICS; CONDUCTANCE; Dielectric relaxation; Tetrabutylammonium bromide; Electrical molar conductivities; Ion solvation; Ion association; Isomers
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:36821
Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons