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Hydration and Counterion Binding of [C12MIM] Micelles

Friesen, Sergej ; Buchecker, Thomas ; Cognigni, Alice ; Bica, Katharina ; Buchner, Richard


Surface-active ionic liquids based on imidazoRum cations are promising targets for micellar catalysis in aqueous solution, yielding enhanced rate constants compared to surfactants based on n-alkyltrimethylammonium cations and exhibiting a pronounced counterion dependence (Bica et al. Chem. Commun. 2012, 48, 5013-5015; Cognigni et al. Phys. Chem. Chem. Phys. 2016, 18, 13375-13384). Probably most ...


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