Polyoxometalates and their interaction with organic molecules and interfaces

Item type:	Thesis of the University of Regensburg (PhD)
Open Access Type:	Primary Publication
Date:	5 August 2020
Referee:	Prof. Dr. Arno Pfitzner
Date of exam:	25 July 2018
Institutions:	Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Keywords:	Polyoxmetalates, Super-chaotropy, Hybrid materials, PNIPAM sheets, Surfactant free microemulsions,
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Yes
Item ID:	37595

Abstract (English)

The general goal of the first part of this PhD thesis was to study in depth the interaction of Polyoxometalates with different type of molecules and interfaces in order to (i) investigate the general concept of super-chaotropy and to (ii) establish how general this concept is. The decisive molecular parameters of POMs were elaborated which influence the strength of POM adsorption on C8EO4 ...

Abstract (English)

The general goal of the first part of this PhD thesis was to study in depth the interaction of Polyoxometalates with different type of molecules and interfaces in order to (i) investigate the general concept of super-chaotropy and to (ii) establish how general this concept is. The decisive molecular parameters of POMs were elaborated which influence the strength of POM adsorption on C8EO4 micelles, polymers, ethylene glycol oligomers and weakly hydrated soft interfaces (surfactant free microemulsions)

Translation of the abstract (German)

Das Ziel der Doktorarbeit war es die Wechselwirkung von Polyoxometallaten mit verschiedenen Grenzflächen und Molekülen zu untersuchen um das Konzept der "Super-Chaotropie" zu untersuchen um festzustellen welche Auswirkungen dieses Konzept hat. Die entscheidenden molekularen Parameter von Polyoxometallaten wurden herausgearbeitet, welche die Adsorptionsstärke von Polyoxometallaten an C8EO4 ...

Translation of the abstract (German)

Das Ziel der Doktorarbeit war es die Wechselwirkung von Polyoxometallaten mit verschiedenen Grenzflächen und Molekülen zu untersuchen um das Konzept der "Super-Chaotropie" zu untersuchen um festzustellen welche Auswirkungen dieses Konzept hat. Die entscheidenden molekularen Parameter von Polyoxometallaten wurden herausgearbeitet, welche die Adsorptionsstärke von Polyoxometallaten an C8EO4 Mizellen, Polymeren, Ethylenglykol Oligomeren und schwach organisierte weiche Grenzflächen (tensidfreie Mikroemulsionslösungen) beeinflussen.

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Abstract (English)

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Translation of the abstract (German)

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