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Development of New Catalytic Systems for the Palladium-Catalyzed Carbonylation of Olefins

Hirschbeck, Vera (2018) Development of New Catalytic Systems for the Palladium-Catalyzed Carbonylation of Olefins. PhD, Universität Regensburg.

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Date of publication of this fulltext: 08 Aug 2018 10:27

Abstract (English)

Herein, different Thio- and Alkoxycarbonylations of olefins have been developed. Therefore, highly active catalytic systems, based on a palladium precursor, a bisphosphine ligand and an acid enabled the transformation of various substrates. Moreover, all reactions proceeds under mild reaction conditions, such as 1 mol% catalyst, ambient temperature and only 2.5 bar of carbon monoxide (CO). In order to prevent working with gaseous CO, N-formylsaccharin was used as a CO-surrogate.

Translation of the abstract (German)

In dieser Arbeit wurden unterschiedliche Thio- und Alkoxycarbonylierungen entwickelt. Sehr effektive Katalysatorsysteme, basierend auf einem Palladium-Vorläufer, einem Bisphosphan-Liganden und einer Säure ermöglichten die Umsetzung von verschiedenen Substraten. Darüber hinaus verlaufen diese Reaktion unter sehr milden Bedingungen, wie 1 mol% Katalysator, Raumtemperatur und nur 2.5 bar ...

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Item type:Thesis of the University of Regensburg (PhD)
Date:8 August 2018
Referee:Prof. Dr. Olga Garcia-Mancheño
Date of exam:2 August 2018
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Dr. Ivana Fleischer
Keywords:Carbonylation, Palladium, Carbon Monoxide, CO-Surrogate, Olefins
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37596
Owner only: item control page

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